He moved to Anson County in 1772.
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Reference: North Carolina Genealogical Society Journal - Aug 1983, pg. 140;

"The W.K. Littleton Collection (P.C. # 227.1) at the N.C. State Archives contains a number of papers of Benjamin Bell of Montgomery Co., N.C.

Among these is a list of "Children Borne to Charles LEDBETTER and his wife Francis" sent "to Mr. Benjamin Bell," who married Charles' daughter, Elizabeth LEDBETTER. Charles and Frances (RANDLE) LEDBETTER moved from Brunswick Co., VA to Montgomery Co., N.C., shortly before the American Revolution (see Roy C. LEDBETTER et al, LEDBETTERS FROM VIRGINIA). The list of Charles' and Frances' children, evidently copied from a family Bible (and which was not known to the authors of LEDBETTERS FROM VIRGINIA)..."
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1782 Montgomery County Tax List
Charles Ledbetter, invalid
560 acres, 15 slaves

Charles Ledbetter is not in the 1810 Montgomery County census.